Alum is found to contain hydrated monovalentcation [M(H2O)6]+, trivalent cation [M’(H2O)6]+3
and SO42– in the ratio of :
Which of the following statements is incorrectin the context of the B-F bond in BF3:-
Which of the following statements is incorrectin relation to the structure of diborane
Borax Na2B4O7 .10H2O is actually
Aluminium is more reactive than iron. Butaluminium is less easily corroded than ironbecause:-
Inorganic graphite is:-
Reactivity of borazole is greater than that ofbenzene because : -
In potash alum, potassium and aluminiumare present as:-
Which of the followiong statements is correct:
On hydrolysis, diborane produces :
Boron has an extremely high melting pointbecause of
Diborane is Lewis acid forming additioncompound B2H6.2NH3with NH3, a Lewis
base. This
Rubies and sapphire are chemically:
Which of the following statements is correctin the context of diborane (B2H6
B2H6
reacts with (CH3)3N to produce:
In BF3
, the B-F bond length is 1.30 Å, whenBF3is allowed to be treated with Me3N, itforms an adduct, Me3N BF3
, The bond
length of B-F in the adduct is:
When an inorganic compound (X) having 3c-2e as well as 2c-2e bonds reacts with
ammonia gas at a certain termperature, givesa compound (Y), isostructural with benzene.Compound (X) with ammonia at a hightemperature produces a substance (Z) :
Among the following compounds of boron,the species which also forms -bond inaddition -bonds is:-
The type of hybridization of boron in diboraneis
Three centre two electron bond(3c – 2e) ispresent in :-
Which of the following is electron deficientcompound :
Which hydride does not exist:
From B2H6
, all the following can be preparedexcept
In B2H6
Aluminium is industrially prepared by
The states of hybridisation of boron andoxygen atoms in boric acid (H3BO3) are
respectively
Aluminium chloride exists as dimer, Al2Cl6insolid state as well as in solution of non-polarsolvents such as benzene. When dissolvedin water, it gives-
The structure of diborane contains
Heating an queous solution of aluminiumchloride to dryness will give :-
Which one of the following is the correctstatement
The role of fluorspar (CaF2
) which is added insmall quantities in the electrolytic reductionof alumina dissolved in fused cryolite(Na3AlF6) is:
The two types of bonds present in B2H6are
covalent and-
Electrolytic reduction of alumina to aluminiumby Hall-Heravlt process is carried out:-
Specify the coordination geometry around andhybridisation of N and B atoms in a 1 : 1complex of BF3and NH3–
H3BO3is :-
B(OH)3
+ NaOH NaBO2
+ Na[B(OH)4] + H2OHow can this reaction is made to proceed inforward direction ?