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CHEMISTRY QUIZ 33 (TOLUENE 1)

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Marks: 200

Q.   1

Q.1 Which type of substitute toluene diazonium chloride reduces with ethanol to give toluene -

Q.   2

Q.2 Toluene may be prepared by -

Q.   3

Q.   4

Q.4 Toluene is mainly obtained by -

Q.   5

Q.5 Reforming of n – octane gives

Q.   6

Q.7 Polystyrene is polymer of –

Q.   7

Q.8 An aromatic hydrocarbon (A) reacts with methyl chloride and anhy. AlCl3 to give an another hydrocarbon (B) whose vapour density is 46. (B) on oxidation gives a compound (C) which on decarboxylation forms (A). Compound (A), (B) and (C) are–

Q.   8

Q.10 Friedel – craft alkylation proceeds through the intermediate formation of -

Q.   9

Q.11 When benzene reacts with an alkyl chloride (RCl) in presence of anhydrous AlCl3 -

Q.   10

Q.12 Which can be used in Friedel – Craft acylation -

Q.   11

Q.13 Which of the following compound is called cumene -

Q.   12

Q.14 Anhydrous AlCl3 is used in the Friedel –Craft's reaction because it is -

Q.   13

Q.   14

Q.16 Ethyl benzene is obtained from benzene and ethyl bromide in presence of -

Q.   15

Q.17 Chlorination of toluene in the presence of light and heat followed by treatment with aq. NaOH gives -

Q.   16

Q.18 Nitration of toluene takes place at -

Q.   17

Q.19 The species responsible for nitration and sulphonation by nitric acid, conc. H2SO4 and fuming H2SO4 are -

Q.   18

Q.20 If the mixture of the following four aromatic compounds on oxidation by strong oxidising agent gives -

Q.   19

Q.21 Methyl group attached to benzene can be oxidised to carboxyl group by reacting with –

Q.   20

Q.   21

Q.23 Which combination is mismatched –

Q.   22

Q.24 When toluene is oxidised with chromyl chloride the product formed is benzaldehyde. The reaction is commonly known as -

Q.   23

Q.25 What is the end product which is obtained on nitration of toluene ?

Q.   24

Q.26 Ozonolysis of toluene gives -

Q.   25

Q.   26

Q.   27

Q.3 Which of the following can be chlorinated most easily in the presence of AlCl3–

Q.   28

Q.   29

Q.5 T.N.T. on explosion gives –

Q.   30

Q.   31

Q.   32

Q.   33

Q.9 Which of the following statements is correct –

Q.   34

Q.10 Etard reaction in the following is –

Q.   35

Q.11 T.N.T. is –

Q.   36

Q.12 Which of the following is o – and p – directing –

Q.   37

Q.13 The highest yield of m– product is possible by the electrophilic substitution of the following –

Q.   38

Q.14 For explosion purpose T.N.T. is mixed with which of the following –

Q.   39

Q.15 Which of the following electrophilic substitution reaction is fastest –

Q.   40

Q.16 Bromination of toluene gives -

Q.   41

Q.17 Toluene when heated with a mixture of fuming HNO3 and fuming H2SO4 to 110o for two hours, gives -

Q.   42

Q.18 Which of the following is the most reactive towards ring nitration ?

Q.   43

Q.19 The reaction of toluene with chlorine in presene of ferric chloride gives predominantly-

Q.   44

Q.20 Toluene when refluxed with Br2 in presence of sunlight mainly gives -

Q.   45

Q.21 A reaction involving chlorobenzene and chloromethane and sodium in dry ether to form toluene is commonly known as -

Q.   46

Q.22 When n-heptane vapours are passed over Pt/Al2O3 at 500oC, the compound formed is-

Q.   47

Q.   48

Q.24 When chlorine is passed in cold toluene in the presence of iodine, the product obtianed is -

Q.   49

Q.25 When benzene is treated with (CH3) 3CCOCl in presence of anhydrous AlCl3 the product obtained is -

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